By Ashot S. Saghyan, Peter Langer
Authored by means of across the world well-known specialists with an outstanding music checklist, this much-needed reference summarizes most up-to-date learn within the swiftly constructing box of stereoselective synthesis of enantiomerically enriched amino acids, quite of non-proteinogenic beginning. It highlights numerous varied catalytic and stoichiometric uneven equipment for his or her synthesis and in addition presents info on beginning, organic homes, varied man made thoughts and significant purposes in drugs and pharmacology.
Essential studying for artificial chemists operating within the box of uneven synthesis, normal items and peptide synthesis, stereochemistry, medicinal chemistry, biochemistry, pharmacology, and biotechnology.
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Additional resources for Asymmetric Synthesis of Non-Proteinogenic Amino Acids
Chem. , 5, 1081. 33 35 3 Systems for Modeling Some Aspects of Pyridoxal Enzyme Action Much of what is known about the pyridoxal catalysis is obtained based on the studies of model systems containing pyridoxal, metal ions, and amino acid. One of the ﬁrst in this respect are the studies of Snell and his students who showed that serine and cysteine in the presence of metal ions and pyridoxal in neutral, acidic, and alkaline environments converted to pyruvic acid [1–3]. Furthermore, it was shown that under the same conditions pyruvic acid was formed by other β-substituted α-amino acids: phosphothreonine , phosphoserine [5–7], β-chloro-α-aminobutyric acid [6, 7], β-chloroalanine [6, 7], S-ethylcysteine , S-phenylcysteine .
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